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CAS 1071-83-6 White Crystalline Powder , Glyphosate Herbicide
Name Abamectin
Glyphosate was first synthesized in 1950 by Swiss chemist Henry Martin, who worked for the Swiss company Cilag. The work was never published.: 1 Stauffer Chemical patented the agent as a chemical chelator in 1964 as it binds and removes minerals such as calcium, magnesium, manganese, copper, and zinc.
Somewhat later, glyphosate was independently discovered in the United States at Monsanto in 1970. Monsanto chemists had synthesized about 100 derivatives of aminomethylphosphonic acid as potential water-softening agents. Two were found to have weak herbicidal activity, and John E. Franz, a chemist at Monsanto, was asked to try to make analogs with stronger herbicidal activity. Glyphosate was the third analog he made.: 1–2 Franz received the National Medal of Technology of the United States in 1987 and the Perkin Medal for Applied Chemistry in 1990 for his discoveries.
Chemical & Physical Properties
Chemical formula
|
C3H8NO5P |
Molar mass | 169.073 g·mol−1 |
Appearance | white crystalline powder |
Density | 1.704 (20 °C) |
Melting point | 184.5 °C (364.1 °F; 457.6 K) |
Boiling point | 187 °C (369 °F; 460 K) decomposes |
Solubility in water
|
1.01 g/100 mL (20 °C) |
log P | −2.8 |
Acidity (pKa) | <2, 2.6, 5.6, 10.6 |
Usage
Glyphosate is effective in killing a wide variety of plants, including grasses and broadleaf and woody plants. By volume, it is one of the most widely used herbicides. In 2007, glyphosate was the most used herbicide in the United States agricultural sector, with 180 to 185 million pounds (82,000 to 84,000 tonnes) applied, the second-most used in home and garden with 5 to 8 million pounds (2,300 to 3,600 tonnes) and 13 to 15 million pounds (5,900 to 6,800 tonnes) in non-agricultural settings.It is commonly used for agriculture, horticulture, viticulture, and silviculture purposes, as well as garden maintenance (including home use). It has a relatively small effect on some clover species and morning glory.
Glyphosate is also used for crop desiccation (siccation) to increase harvest yield and uniformity.Glyphosate itself is not a chemical desiccant; rather glyphosate application just before harvest kills the crop plants so that the food crop dries from environmental conditions ("dry-down") more quickly and evenly.Because glyphosate is systemic, excess residue levels can persist in plants due to incorrect application and this may render the crop unfit for sale.When applied appropriately, it can promote useful effects. In sugarcane, for example, glyphosate application increases sucrose concentration before harvest.In grain crops (wheat, barley, oats), uniformly dried crops do not have to be windrowed (swathed and dried) prior to harvest, but can easily be straight-cut and harvested. This saves the farmer time and money, which is important in northern regions where the growing season is short, and it enhances grain storage when the grain has a lower and more uniform moisture content.